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changsha langfeng metallic material Zirconium carbide powder introduction

2015-10-26




Zirconium carbide (ZrC) is an extremely hard refractory ceramic material,commercially used in tool bits for cutting tools. It is usually processed by sintering.


It has the appearance of a gray metallic powder with cubic crystal structure. It is highly corrosion resistant. This Group IV interstitial transition-metal carbide is also a member of ultra high temperature ceramics or (UHTC). Due to the presence of metallic bonding, ZrC has a thermal conductivity of 20.5 W/m· K and an electrical conductivity (resistivity ~43 &mu &Omega · cm), both of which are similar to that for zirconium metal. The strong covalent Zr-C bond gives this material a very high melting point (~3530 ° C), high modulus (~440 GPa) and hardness (25 GPa). ZrC has a lower density (6.73 g/cm3) compared to other carbides like WC (15.8 g/cm3), TaC (14.5 g/cm3) or HfC (12.67 g/cm3). ZrC seems suitable for use in re-entry vehicles, rocket/SCRAM jet engines or supersonic vehicles in which low densities and high temperatures load-bearing capabilities are crucial requirements.

Like most carbides of refractory metals, zirconium carbide is sub-stoichiometric, i.e., it contains carbon vacancies. At carbon contents higher than approximately ZrC0.98 the material contains free carbon.[5] ZrC is stable for a carbon-to-metal ratio ranging from 0.65 to 0.98.

ZrC reacts with water and acids and is pyrophoric.


The mixture of zirconium carbide and tantalum carbide is an important cermet material.

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